Fluid generation and evolution during exhumation of deeply subducted UHP continental crust: Petrogenesis of composite granite–quartz veins in the Sulu belt,China          下载免费PDF全文

S.‐J. Wang  L. Wang  M. Brown  P. M. Piccoli  T. E. Johnson  P. Feng  H. Deng  K. Kitajima  Y. Huang 《Journal of Metamorphic Geology》2017,35(6):601-629

Composite granite–quartz veins occur in retrogressed ultrahigh pressure (UHP) eclogite enclosed in gneiss at General's Hill in the central Sulu belt, eastern China. The granite in the veins has a high‐pressure (HP) mineral assemblage of dominantly quartz+phengite+allanite/epidote+garnet that yields pressures of 2.5–2.1 GPa (Si‐in‐phengite barometry) and temperatures of 850–780°C (Ti‐in‐zircon thermometry) at 2.5 GPa (~20°C lower at 2.1 GPa). Zircon overgrowths on inherited cores and new grains of zircon from both components of the composite veins crystallized at c. 221 Ma. This age overlaps the timing of HP retrograde recrystallization dated at 225–215 Ma from multiple localities in the Sulu belt, consistent with the HP conditions retrieved from the granite. The ε_Hf(t) values of new zircon from both components of the composite veins and the Sr–Nd isotope compositions of the granite consistently lie between values for gneiss and eclogite, whereas δ¹⁸O values of new zircon are similar in the veins and the crustal rocks. These data are consistent with zircon growth from a blended fluid generated internally within the gneiss and the eclogite, without any ingress of fluid from an external source. However, at the peak metamorphic pressure, which could have reached 7 GPa, the rocks were likely fluid absent. During initial exhumation under UHP conditions, exsolution of H₂O from nominally anhydrous minerals generated a grain boundary supercritical fluid in both gneiss and eclogite. As exhumation progressed, the volume of fluid increased allowing it to migrate by diffusing porous flow from grain boundaries into channels and drain from the dominant gneiss through the subordinate eclogite. This produced a blended fluid intermediate in its isotope composition between the two end‐members, as recorded by the composite veins. During exhumation from UHP (coesite) eclogite to HP (quartz) eclogite facies conditions, the supercritical fluid evolved by dissolution of the silicate mineral matrix, becoming increasingly solute‐rich, more ‘granitic’ and more viscous until it became trapped. As crystallization began by diffusive loss of H₂O to the host eclogite concomitant with ongoing exhumation of the crust, the trapped supercritical fluid intersected the solvus for the granite–H₂O system, allowing phase separation and formation of the composite granite–quartz veins. Subsequently, during the transition from HP eclogite to amphibolite facies conditions, minor phengite breakdown melting is recorded in both the granite and the gneiss by K‐feldspar+plagioclase+biotite aggregates located around phengite and by K‐feldspar veinlets along grain boundaries. Phase equilibria modelling of the granite indicates that this late‐stage melting records P–T conditions towards the end of the exhumation, with the subsolidus assemblage yielding 0.7–1.1 GPa at <670°C. Thus, the composite granite–quartz veins represent a rare example of a natural system recording how the fluid phase evolved during exhumation of continental crust. The successive availability of different fluid phases attending retrograde metamorphism from UHP eclogite to amphibolite facies conditions will affect the transport of trace elements through the continental crust and the role of these fluids as metasomatic agents interacting with the mantle wedge in the subduction channel.  相似文献   

海水温度对衰亡期浒苔释放生源硫影响的模拟研究   总被引：1，自引：0，他引：1  

韩露  邓雪  李培峰  高先池  刘春颖 《海洋学报》2018,40(10):110-118

为研究浒苔释放生源硫的特征，本文对采集于黄海绿潮中期和末期的浒苔进行了实验室模拟培养，探讨了不同温度对衰亡期浒苔释放生源硫化物的影响。实验结果表明，在10~25℃温度范围内，温度升高能够加速浒苔的衰亡。二甲基硫（DMS）的平均释放速率范围为2.79~150.70 nmol/（L·g·d），二甲基硫基丙酸内盐（DMSP）的平均释放速率范围为2.16~113.26 nmol/（L·g·d）。温度升高能够使DMS和DMSP的释放速率加快，释放量增加，DMS最大平均释放速率在25℃条件下比10℃条件下升高了约60%，培养液中DMS浓度升高了2~3倍。采集于绿潮末期的浒苔培养液中的DMS和DMSP和采集于绿潮中期的浒苔相比，浓度有所增加，采集于浒苔绿潮末期浒苔培养液中DMS的最高平均浓度为418.41 nmol/L，约为中期的4倍；DMSP的最高平均浓度为316.14 nmol/L，是中期的3倍。浒苔绿潮的爆发会对水体中的硫体系循环产生影响，进而影响该海域生态环境。  相似文献   

Modelling spatial variations in dissolved oxygen in fine‐grained streams under uncertainty          下载免费PDF全文

Vahid Zahraeifard  Zhiqiang Deng  Ronald Malone 《水文研究》2015,29(2):212-224

This paper presents a novel triple‐layer model, called VART DO‐3L, for simulation of spatial variations in dissolved oxygen (DO) in fine‐grained streams, characterized by a fluid mud (fluff or flocculent) layer (an advection‐dominated storage zone) as the interface between overlying stream water and relatively consolidated streambed sediment (a diffusion‐dominated storage zone). A global sensitivity analysis is conducted to investigate the sensitivity of VART DO‐3L model input parameters. Results of the sensitivity analysis indicate that the most sensitive parameter is the relative size of the advection‐dominated storage zones (A_s/A), followed by a lumped reaction term (R) for the flocculent layer, biological reaction rate (μ_o) in diffusive layer and biochemical oxygen demand concentration (L) in water column. In order to address uncertainty in model input parameters, Monte Carlo simulations are performed to sample parameter values and to produce various parameter combinations or cases. The VART DO‐3L model is applied to the Lower Amite River in Louisiana, USA, to simulate vertical and longitudinal variations in DO under the cases. In terms of longitudinal variation, the DO level decreases from 7.9 mg l at the Denham Springs station to about 2.89 mg l^?1 at the Port Vincent station. In terms of vertical variation, the DO level drops rapidly from the overlying water column to the advection‐dominated storage zone and further to the diffusive layer. The DO level (C_F) in the advective layer (flocculent layer) can reach as high as 40% of DO concentration (C) in the water column. The VART DO‐3L model may be applied to similar rivers for simulation of spatial variations in DO level. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Composition and flux of suspended organic matter in the middle and lower reaches of the Changjiang (Yangtze River) — impact of the Three Gorges Dam and the role of tributaries and channel erosion          下载免费PDF全文

Hongyan Bao  Ying Wu  Jing Zhang  Bing Deng  Qing He 《水文研究》2014,28(3):1137-1147

To investigate the sources of particulate organic matter (POM) and the impact of Three Gorges Dam (TGD), two large lakes and erosion processes on determining the composition and flux of POM in low water discharge periods along the middle and lower Changjiang, suspended particulate samples were collected along the middle and lower reaches of the Changjiang (Yangtze River) in January 2008. Organic geochemistry of bulk sediment (particulate organic carbon, organic carbon to nitrogen molar ratio (C/N), stable carbon isotope (δ¹³C) and grain size) and biomarker of bulk sediment (lignin phenols) were measured to trace the sources of POM. The range of C/N ratios (6.4–8.9), δ¹³C (?24.3‰ – ?26.2‰) and lignin phenols concentration Λ8 (0.45 mg/100 mg OC‐2.00 mg/100 mg OC) of POM suggested that POM originated from the mixture of soil, plant tissue and autochthonous organic matter (OM) during the dry season. POM from lakes contained a higher portion of terrestrial OM than the mainstream, which was related to sand mining and hydropower erosion processes. A three end‐member model based on δ¹³C and Λ8 was performed. The results indicated that soil contributed approximately 50% of OM to the POM, which is the dominant OM source in most stations. POM composition was affected by total suspended matter (TSM) and grain size composition, and the direct OM input from two lakes and channel erosion induced OM. The lower TSM concentration in January 2008 was mainly caused by seasonal variations; the impact from the TGD in the dry season was relatively small. A box model indicated that more than 90% of the terrestrial OM transported by the Changjiang in January 2008 was from the middle and lower drainage basins. Channel erosion induced OM, and contributions from Poyang Lake were the major terrestrial OM sources in the dry season. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

西太平洋海域现场培养实验中挥发性卤代烃浓度的变化及其影响因素     

韩钰  何真  刘珊珊  高旭旭  杨桂朋 《海洋学报》2020,42(2):1-9

CH₃I、CHCl₃、C₂HCl₃和CH₂Br₂是挥发性卤代烃4种重要成分，对大气化学产生重要影响。于2018年10月在西太平洋进行船基现场培养实验，研究微量元素Fe (50 nmol/L)、酸化(pH=7.9)、酸化(pH=7.9)和微量元素Fe (50 nmol/L)耦合作用、微量元素Fe (50 nmol/L)和N/P (16∶1)耦合作用及沙尘(4 mg/L)对浮游植物释放CH₃I、CHCl₃、C₂HCl₃和CH₂Br₂含量的影响。结果表明，与对照组相比，实验组CH₃I、C₂HCl₃和CH₂Br₂的释放均被不同程度抑制；CHCl₃的释放除添加沙尘时表现抑制作用外，其他条件下均为促进作用；实验组培养周期内叶绿素a浓度较高，而营养盐浓度变化规律不明显。总的来说，酸化和微量元素Fe可能是影响浮游植物释放挥发性卤代烃的重要限制因素，沙尘对促进浮游植物生长繁殖的影响更为显著。  相似文献   

Impacts of confining pressure and safety thickness on water and mud inrush in weathered granite     

Jinquan Liu  Weizhong Chen  Zhiping Deng  Taogen Liu 《Marine Georesources & Geotechnology》2020,38(2):144-153

Abstract

Due to the strong disintegration and water erosion of completely weathered granite, water and mud inrush disasters are apt to take place in this zone during underwater tunnel construction. The pore, compactness, seepage path length, fracture geometries and their interconnections for water and mud transfer are strongly influenced by confining pressure and waterproof-resistant slab safety thickness. In order to inspect the influence, a series of experiments based on a self-designed testing system and non-Darcy testing method were performed. The results indicated that the water and mud inrush evolution increased with the increase of confining pressure and decreased with the increase of safety thickness. In particular, the confining pressure mainly influences the initial evolution stage, and a critical safety thickness to prevent water and mud inrush is obtained. Besides, the non-Darcy testing method results shows that the water and mud inrush evolution affects the influence of non-Darcy flow. For example, while the safety thickness was smaller than the critical value, the evolution was large and unstable and its behavior transferred into nonlinear. In this case, the flow changed to non-Darcy flow.  相似文献   

Study on Nonlinear Characteristics of Freak-Wave Forces with Different Wave Steepness     

Deng  Yan-fei  Tian  Xin-liang  Li  Xin 《中国海洋工程》2019,33(5):608-617

The nonlinear wave forces on vertical cylinders induced by freak wave trains were experimentally investigated. A series of freak wave trains with different wave steepness were modeled in a wave flume. The corresponding wave forces on vertical cylinders of different diameters were measured. The experimental wave forces were also compared with the predicted results based on Morison formula. Particular attentions were paid to the effects of wave steepness on the dimensionless peak forces, asymmetry characteristics of the impact forces and high-frequency force components. Wavelet-based analysis methods were employed in revealing the local energy structures and quadratic phase coupling in the freak wave forces.  相似文献   

臭氧及臭氧类高级氧化技术降解甲基对硫磷的效能          下载免费PDF全文

林存旺  许珊珊  项丰云  章小芳 《海洋开发与管理》2018,35(9):94-99

文章研究了臭氧及臭氧类高级氧化技术(AOPs-O3)在不同pH条件下降解甲基对硫磷(MP)的效能。结果表明,在pH 3~10的条件下(反应过程控制pH),单独臭氧化5min即可完全降解MP,但不同pH下化学耗氧量(COD)和有机磷的释放率差异明显。在pH为3.3,7.5和9.4的条件下单独臭氧30min后COD的去除率分别为55.17%,89.64%和93.10%,有机磷的释放率分别为16.33%,95.00%和99.99%。考虑酸性条件下可以规避碳酸盐的负面影响(特别是高浓度废水),利用O3/H2O2/Ti(IV)在pH 3.3条件下处理MP溶液,COD去除率和有机磷释放率分别达到89.64%和81.57%。相对法计算求得MP与O3和羟基自由基(·OH)的速率常数分别为31.98L·(mol·s)-1和7.488×109 L·(mol·s)-1。活性污泥法的测试结果表明,MP经O3/Ti(IV)/H2O2(pH=3.3)和O3(pH=9.4)可提升含MP废水的可生化性,但与培养液体系相比仍具有一定的毒性。  相似文献   

Flotation characteristics of two different types of ilmenite with sodium oleate     

Zhang Jie  Liu Weijun  Wang Weiqing  Xiong shuqing  Wang dezhi  Yan Wu  Deng Jie 《Mineralogy and Petrology》2015,109(3):299-306

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Changes in potential evapotranspiration and surface runoff in 1981–2010 and the driving factors in Upper Heihe River Basin in Northwest China          下载免费PDF全文

Kaisheng Luo  Fulu Tao  Xiangzheng Deng  Juana P. Moiwo 《水文研究》2017,31(1):90-103

Changes in potential evapotranspiration and surface runoff can have profound implications for hydrological processes in arid and semiarid regions. In this study, we investigated the response of hydrological processes to climate change in Upper Heihe River Basin in Northwest China for the period from 1981 to 2010. We used agronomic, climatic and hydrological data to drive the Soil and Water Assessment Tool model for changes in potential evapotranspiration (ET₀) and surface runoff and the driving factors in the study area. The results showed that increasing autumn temperature increased snow melt, resulting in increased surface runoff, especially in September and October. The spatial distribution of annual runoff was different from that of seasonal runoff, with the highest runoff in Yeniugou River, followed by Babaohe River and then the tributaries in the northern of the basin. There was no evaporation paradox at annual and seasonal time scales, and annual ET₀ was driven mainly by wind speed. ET₀ was driven by relative humidity in spring, sunshine hour duration in autumn and both sunshine hour duration and relative humility in summer. Surface runoff was controlled by temperature in spring and winter and by precipitation in summer (flood season). Although surface runoff increased in autumn with increasing temperature, it depended on rainfall in September and on temperature in October and November. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献